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Frequency Security-Aware Production Scheduling of Utility-Scale Off-Grid Renewable P2H Systems Coordinating Heterogeneous Electrolyzers

Jie Zhu, Yiwei Qiu, Yangjun Zeng, Shahab Dehghan, Sheng Wang, Shi Chen, Buxiang Zhou

Abstract

Renewable power-to-hydrogen (ReP2H) enables large-scale renewable energy utilization and supports the decarbonization of hard-to-abate sectors, such as chemicals and maritime transport, via hydrogen-based renewable ammonia and methanol fuels. As a result, utility-scale ReP2H projects are expanding worldwide. However, off-grid ReP2H systems exhibit low inertia due to their converter-dominated nature, making frequency security a critical concern. Although recent studies show that electrolyzers can contribute to frequency regulation (FR), their support capability depends on operating states and loading levels, creating a trade-off between hydrogen output and frequency security. To address this challenge, this work develops a unified co-optimization framework for frequency security-aware production scheduling of utility-scale off-grid ReP2H systems coordinating heterogeneous electrolyzers. A system-level frequency response model is established to capture multi-stage FR from alkaline water electrolyzers (AWEs), proton exchange membrane electrolyzers (PEMELs), and other resources, including ammonia-fueled generators retrofitted in co-located chemical plants, battery energy storage, and wind turbines (WTs). Stage-wise transient frequency security constraints are derived, reformulated into tractable forms, and embedded into production scheduling, enabling coordinated on/off switching and load allocation across electrolyzers to maximize hydrogen output under uncertain renewable power input while enforcing frequency security constraints. Case studies based on real-world systems demonstrate that the proposed approach allows HPs to replace 55.52% and 96.85% of FR reserves from WTs and AFGs, respectively, while maintaining comparable hydrogen output. Year-long simulations show an average 28.96% increase in annual net profit resulting from reduced reliance on conventional reserves.

Frequency Security-Aware Production Scheduling of Utility-Scale Off-Grid Renewable P2H Systems Coordinating Heterogeneous Electrolyzers

Abstract

Renewable power-to-hydrogen (ReP2H) enables large-scale renewable energy utilization and supports the decarbonization of hard-to-abate sectors, such as chemicals and maritime transport, via hydrogen-based renewable ammonia and methanol fuels. As a result, utility-scale ReP2H projects are expanding worldwide. However, off-grid ReP2H systems exhibit low inertia due to their converter-dominated nature, making frequency security a critical concern. Although recent studies show that electrolyzers can contribute to frequency regulation (FR), their support capability depends on operating states and loading levels, creating a trade-off between hydrogen output and frequency security. To address this challenge, this work develops a unified co-optimization framework for frequency security-aware production scheduling of utility-scale off-grid ReP2H systems coordinating heterogeneous electrolyzers. A system-level frequency response model is established to capture multi-stage FR from alkaline water electrolyzers (AWEs), proton exchange membrane electrolyzers (PEMELs), and other resources, including ammonia-fueled generators retrofitted in co-located chemical plants, battery energy storage, and wind turbines (WTs). Stage-wise transient frequency security constraints are derived, reformulated into tractable forms, and embedded into production scheduling, enabling coordinated on/off switching and load allocation across electrolyzers to maximize hydrogen output under uncertain renewable power input while enforcing frequency security constraints. Case studies based on real-world systems demonstrate that the proposed approach allows HPs to replace 55.52% and 96.85% of FR reserves from WTs and AFGs, respectively, while maintaining comparable hydrogen output. Year-long simulations show an average 28.96% increase in annual net profit resulting from reduced reliance on conventional reserves.
Paper Structure (28 sections, 1 theorem, 50 equations, 15 figures, 5 tables)

This paper contains 28 sections, 1 theorem, 50 equations, 15 figures, 5 tables.

Key Result

Proposition 1

Let $\tau_{\mathrm{nadir}}(H,R_1)$ denote eq:26 under a known $\Delta P_{\mathrm{dis}}$. For any $\Delta P_{\mathrm{dis}}>0$ and $H>0$, there exists a unique $R_1^*(H)>0$ such that $\tau_{\mathrm{nadir}}(H,R_1^*(H))=t_{\mathrm{DB2}}$, as shown in Fig. fig:FrequencyInterval(b). Define $R_1^{\mathrm{l Moreover, there exists a small time margin $\mu\ge 0$ such that for any $R_1\in(R_1^{\mathrm{lo}},R

Figures (15)

  • Figure 1: Schematic diagram of a typical off-grid ReP2H system.
  • Figure 2: Frequency control and dynamic load response of electrolyzers. (a) Frequency control diagram. (b) Equivalent circuit of the electrolysis stack. (c) Step responses of the AWE and PEMEL.
  • Figure 3: AWE Stack efficiency with different current density and temperature.
  • Figure 4: Comparison of the post-contingency frequency dynamics and PFR power under the proposed model \ref{['eq:22']} and the EMT benchmark. (a) Post-contingency frequency. (b) PFR power of AWEs. (c) PFR power of AFGs.
  • Figure 5: Frequency nadir dynamics. (a) Occurrence cases of the frequency nadir. (b) Time of the frequency nadir with varying reserve and inertia levels.
  • ...and 10 more figures

Theorems & Definitions (3)

  • Remark 1
  • Proposition 1
  • proof