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Breit corrections to moderately charged ions in all-orders calculations

Andoni Skoufris, Benjamin M. Roberts

Abstract

The atomic properties of heavy, moderately-charged ions are important for a wide variety of applications, including precision tests of fundamental physics and for the study and development of atomic and nuclear clocks. In these systems it is known that relativistic effects, such as the Breit interaction and radiative quantum electrodynamics corrections, are important for an accurate understanding of atomic properties. It is also known that inclusion of correlations alongside the Breit effect is crucial. In this work we include the Breit interaction into all-orders calculations of energy levels and fine structure intervals of ions in the Cs and Fr isoelectronic sequences. This requires modifying the electron Green's function to account for Breit within the all-orders correlation potential method, which sums dominating series of perturbation diagrams exactly using a Feynman diagram technique. We find that Breit corrections to the energies of moderately ionized ions along these sequences are very large, particularly for the f states. We also observe a significant deviation from experiment for these levels. Incorporating Breit into the all-orders correlation potential provides a significant additional contribution beyond including Breit at the second-order level alone. While this does not resolve the disagreement in the energy levels, it does substantially improve the fine-structure intervals beyond what is achieved by including Breit only at second order. Furthermore, we include the frequency-dependent Breit interaction into the Dirac-Fock procedure, and find that this does not significantly modify the energy levels at this order of approximation.

Breit corrections to moderately charged ions in all-orders calculations

Abstract

The atomic properties of heavy, moderately-charged ions are important for a wide variety of applications, including precision tests of fundamental physics and for the study and development of atomic and nuclear clocks. In these systems it is known that relativistic effects, such as the Breit interaction and radiative quantum electrodynamics corrections, are important for an accurate understanding of atomic properties. It is also known that inclusion of correlations alongside the Breit effect is crucial. In this work we include the Breit interaction into all-orders calculations of energy levels and fine structure intervals of ions in the Cs and Fr isoelectronic sequences. This requires modifying the electron Green's function to account for Breit within the all-orders correlation potential method, which sums dominating series of perturbation diagrams exactly using a Feynman diagram technique. We find that Breit corrections to the energies of moderately ionized ions along these sequences are very large, particularly for the f states. We also observe a significant deviation from experiment for these levels. Incorporating Breit into the all-orders correlation potential provides a significant additional contribution beyond including Breit at the second-order level alone. While this does not resolve the disagreement in the energy levels, it does substantially improve the fine-structure intervals beyond what is achieved by including Breit only at second order. Furthermore, we include the frequency-dependent Breit interaction into the Dirac-Fock procedure, and find that this does not significantly modify the energy levels at this order of approximation.
Paper Structure (10 sections, 18 equations, 3 figures, 6 tables)

This paper contains 10 sections, 18 equations, 3 figures, 6 tables.

Table of Contents

  1. Introduction
  2. Theory
  3. Breit into correlations: second-order
  4. Breit into all-orders correlations
  5. Results and Discussion
  6. Energies
  7. Fine structure intervals
  8. Additional relativistic corrections
  9. Numerical results
  10. Conclusion

Figures (3)

  • Figure 1: Feynman diagrams representing the direct (left) and exchange (right) contributions to the second order correlation correction to the energy of a single valence state.
  • Figure 2: All-orders screening of the Coulomb operator (top) and hole-particle interaction (bottom).
  • Figure 3: Feynman diagrams for the direct (left) and exchange (right) all-orders correlation corrections.