Determinant and Pfaffian formulas for particle annihilation
Piotr Śniady
TL;DR
This work develops exact finite-configurations for one-dimensional annihilating random walks by introducing ghost particles that preserve a fixed entity count, enabling determinantal formulas for annihilation outcomes. The central result is an annihilation formula expressed as a determinant with formal variables that filter to the physically admissible ghost configurations; a Pfaffian form emerges in the complete-annihilation limit, linking to Pfaffian point process theory. The authors also establish a deep connection between annihilation and coalescence through a parity-based reclassification, deriving a Pfaffian formula for pairwise coalescence and highlighting a broader determinant–Pfaffian spectrum across models. The framework applies to discrete lattice paths, birth–death chains, and Brownian motion, and it offers exact, finite-time probabilities for domain-wall dynamics and reaction–diffusion systems, with companion papers extending the approach to gaps and continuous-time settings.
Abstract
When particles on a line collide, they may annihilate-both are destroyed. Computing exact annihilation probabilities has been difficult because collisions reduce the particle count, while determinantal methods require a fixed count throughout. The ghost particle method, introduced in a companion paper for coalescence, keeps destroyed particles walking as invisible ghosts that restore the missing dimension. We apply this method to annihilation: when two particles annihilate, both trajectories continue as invisible walkers, yielding an exact determinantal formula that specifies the number of annihilations, where survivors end up, and where ghosts end up. For complete annihilation (no survivors), the formula simplifies to a Pfaffian-an algebraic relative of the determinant built from pairwise quantities-connecting to Pfaffian point process theory. The annihilation formula also yields results about coalescence: pairwise coalescence can be reinterpreted as complete annihilation, producing a Pfaffian coalescence formula. These formulas are exact for any finite initial configuration and apply to discrete lattice paths, birth-death chains, and continuous diffusions including Brownian motion.
