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A kinetic-moment framework for electron energy dynamics in capacitively coupled plasmas: absorption, conversion, transport, and dissipation

Jianxiong Yao, Zeduan Zhang, Feng He, Jinsong Miao, Jiting Ouyang, Bocong Zheng

TL;DR

The study tackles how electron energy is absorbed, converted, transported, and dissipated in low-pressure capacitively coupled plasmas, where the energy source is $\boldsymbol J\cdot\boldsymbol E$ and energy redistribution occurs through kinetic and thermal channels. It introduces a kinetic-moment framework that reconstructs the first three velocity moments from PIC/MCC data and decouples the total energy transport into directed kinetic energy $\rho_{\varepsilon,\mathrm{k}}$ and thermal energy $\rho_{\varepsilon,\mathrm{th}}$, yielding decoupled transport equations. The results show localized sheath absorption, rapid local kinetic-to-thermal conversion via pressure-strain interaction and collisions, and nonlocal thermal-energy transport carried by a third-moment heat flux $\boldsymbol q=\tfrac12\rho_m\langle w^2\boldsymbol w\rangle$, with dissipation dominated by inelastic collisions in the bulk. This framework provides a self-consistent, kinetically faithful description of energy evolution in nonequilibrium CCPs and offers a robust benchmark for fluid and hybrid models, with potential extensions to multi-dimensional geometries, magnetized plasmas, and more complex chemistry.

Abstract

Understanding electron energy dynamics in low-temperature plasmas such as capacitively coupled plasmas (CCPs), including energy absorption, conversion, transport, and dissipation, is essential for interpreting discharge physics and process applications. We propose a kinetic-moment framework based on particle-in-cell/Monte Carlo collision (PIC/MCC) simulations. The framework reconstructs the first three velocity moments of the Boltzmann equation directly from PIC/MCC data and enables a quantitative, self-consistent description of electron energy dynamics in low-pressure CCPs. To clarify energy conversion among electromagnetic energy, electron fluid kinetic (mechanical) energy, and electron thermal (internal) energy, we further separate the total energy transport equation into kinetic- and thermal-energy equations. We find that, at low pressure, electrons gain directed kinetic energy in the sheath and convert it locally into thermal energy through pressure-strain interaction and collisions. Thermal energy is then transported into the bulk and is dissipated mainly by inelastic electron-neutral collisions. We further decompose pressure-strain interaction into reversible pressure dilatation and irreversible viscous-like dissipation, which correspond to conversion driven by volumetric compression or expansion and by shear deformation, respectively. This decomposition reveals a significant thermalization channel beyond collisions. More broadly, the results show coexistence of localized kinetic-to-thermal conversion near the sheath and nonlocal energy transport from the sheath to the bulk dominated by microscopic heat flux. The heat flux deviates strongly from Fourier's law based on local temperature gradients. This framework provides a clear fluid description with kinetic fidelity and offers a practical tool for analyzing energy evolution in nonequilibrium plasmas.

A kinetic-moment framework for electron energy dynamics in capacitively coupled plasmas: absorption, conversion, transport, and dissipation

TL;DR

The study tackles how electron energy is absorbed, converted, transported, and dissipated in low-pressure capacitively coupled plasmas, where the energy source is and energy redistribution occurs through kinetic and thermal channels. It introduces a kinetic-moment framework that reconstructs the first three velocity moments from PIC/MCC data and decouples the total energy transport into directed kinetic energy and thermal energy , yielding decoupled transport equations. The results show localized sheath absorption, rapid local kinetic-to-thermal conversion via pressure-strain interaction and collisions, and nonlocal thermal-energy transport carried by a third-moment heat flux , with dissipation dominated by inelastic collisions in the bulk. This framework provides a self-consistent, kinetically faithful description of energy evolution in nonequilibrium CCPs and offers a robust benchmark for fluid and hybrid models, with potential extensions to multi-dimensional geometries, magnetized plasmas, and more complex chemistry.

Abstract

Understanding electron energy dynamics in low-temperature plasmas such as capacitively coupled plasmas (CCPs), including energy absorption, conversion, transport, and dissipation, is essential for interpreting discharge physics and process applications. We propose a kinetic-moment framework based on particle-in-cell/Monte Carlo collision (PIC/MCC) simulations. The framework reconstructs the first three velocity moments of the Boltzmann equation directly from PIC/MCC data and enables a quantitative, self-consistent description of electron energy dynamics in low-pressure CCPs. To clarify energy conversion among electromagnetic energy, electron fluid kinetic (mechanical) energy, and electron thermal (internal) energy, we further separate the total energy transport equation into kinetic- and thermal-energy equations. We find that, at low pressure, electrons gain directed kinetic energy in the sheath and convert it locally into thermal energy through pressure-strain interaction and collisions. Thermal energy is then transported into the bulk and is dissipated mainly by inelastic electron-neutral collisions. We further decompose pressure-strain interaction into reversible pressure dilatation and irreversible viscous-like dissipation, which correspond to conversion driven by volumetric compression or expansion and by shear deformation, respectively. This decomposition reveals a significant thermalization channel beyond collisions. More broadly, the results show coexistence of localized kinetic-to-thermal conversion near the sheath and nonlocal energy transport from the sheath to the bulk dominated by microscopic heat flux. The heat flux deviates strongly from Fourier's law based on local temperature gradients. This framework provides a clear fluid description with kinetic fidelity and offers a practical tool for analyzing energy evolution in nonequilibrium plasmas.
Paper Structure (11 sections, 20 equations, 10 figures)

This paper contains 11 sections, 20 equations, 10 figures.

Figures (10)

  • Figure 1: Spatiotemporal distributions of energy density $\rho_\varepsilon$ (a) and each transport term (b-d) corresponding to energy transport equation \ref{['eq:EnergyTransportEq']} for electrons.
  • Figure 2: Time-averaged spatial profile (a) and space-averaged temporal evolution (b) of energy transport terms for electrons. The numbered labels in the figure correspond to the terms in energy transport equation \ref{['eq:EnergyTransportEq']}.
  • Figure 3: Spatiotemporal distributions of kinetic energy density $\rho_{\varepsilon, \mathrm k}$ (a) and each transport term (b-h) corresponding to kinetic energy transport equation \ref{['eq:KineticTransportEq']} for electrons.
  • Figure 4: Time-averaged spatial profile (a) and space-averaged temporal evolution (b) of kinetic energy transport terms for electrons. The numbered labels in the figure correspond to the terms in kinetic energy transport equation \ref{['eq:KineticTransportEq']}.
  • Figure 5: Spatiotemporal distributions of individual split terms of pressure--strain interaction corresponding to equation \ref{['eq:StressStrainInteraction']} for electrons.
  • ...and 5 more figures