Additive-Functional Approach to Transport in Periodic and Tilted Periodic Potentials

Abstract

We present a unified theoretical framework for effective transport in periodic and tilted periodic potentials based on additive functionals of stochastic processes. By systematically combining the Poisson equation, corrector construction, and martingale decomposition, we show that both the long-time drift and diffusion of overdamped Brownian motion can be derived within a single and transparent scheme. In the absence of external tilt, the formalism naturally recovers the classical Lifson-Jackson formula for the effective diffusion coefficient. When a constant bias is applied, breaking detailed balance and inducing a finite stationary current, the same approach yields the Stratonovich expressions for the effective drift and diffusion in tilted periodic potentials. Beyond one dimension, we demonstrate that the same additive-functional structure extends directly to two-dimensional and general N dimensional periodic diffusions, leading to the standard homogenized drift and diffusion tensor expressed in terms of vector-valued correctors. Our derivation highlights the central role of additive functionals in separating bounded microscopic corrections from unbounded macroscopic transport and clarifies the connection between reversible and nonequilibrium steady states. This work provides a conceptually unified and mathematically controlled route to transport coefficients in periodic media, with direct relevance to stochastic transport, soft matter, and nonequilibrium statistical physics.