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High-Efficiency Three-Stroke Quantum Isochoric Heat Engine: From Infinite Potential Wells to Magic Angle Twisted Bilayer Graphene

Hadi Mohammed Soufy, Colin Benjamin

Abstract

We introduce a three-stroke quantum isochoric cycle that functions as a heat engine operating between two thermal reservoirs. Implemented for a particle confined in a one-dimensional infinite potential well, the cycle's performance is benchmarked against the classical three-stroke triangular and isochoric engines. We find that the quantum isochoric cycle achieves a higher efficiency than both classical counterparts and also surpasses the efficiency of the recently proposed three-stroke quantum isoenergetic cycle. Owing to its reduced number of strokes, the design substantially lowers control complexity in nanoscale thermodynamic devices, offering a more feasible route to experimental realization compared to conventional four-stroke architectures. We further evaluate the cycle in graphene-based systems under an external magnetic field, including monolayer graphene (MLG), AB-stacked bilayer graphene (BLG), and twisted bilayer graphene (TBG) at both magic and non-magic twist angles. Among these platforms, magic-angle twisted bilayer graphene (MATBG) attains the highest efficiency at fixed work output, highlighting its promise for quantum thermodynamic applications.

High-Efficiency Three-Stroke Quantum Isochoric Heat Engine: From Infinite Potential Wells to Magic Angle Twisted Bilayer Graphene

Abstract

We introduce a three-stroke quantum isochoric cycle that functions as a heat engine operating between two thermal reservoirs. Implemented for a particle confined in a one-dimensional infinite potential well, the cycle's performance is benchmarked against the classical three-stroke triangular and isochoric engines. We find that the quantum isochoric cycle achieves a higher efficiency than both classical counterparts and also surpasses the efficiency of the recently proposed three-stroke quantum isoenergetic cycle. Owing to its reduced number of strokes, the design substantially lowers control complexity in nanoscale thermodynamic devices, offering a more feasible route to experimental realization compared to conventional four-stroke architectures. We further evaluate the cycle in graphene-based systems under an external magnetic field, including monolayer graphene (MLG), AB-stacked bilayer graphene (BLG), and twisted bilayer graphene (TBG) at both magic and non-magic twist angles. Among these platforms, magic-angle twisted bilayer graphene (MATBG) attains the highest efficiency at fixed work output, highlighting its promise for quantum thermodynamic applications.

Paper Structure

This paper contains 10 sections, 50 equations, 12 figures, 3 tables.

Figures (12)

  • Figure 1: Entropy - Temperature (T-S) diagrams for three thermodynamic cycles. Shown are: the classical triangular cycle $A \to B \xrightarrow{\text{Blue}} C \to A$rau2017statistical, the classical isochoric cycle $A \to B \xrightarrow{\text{Yellow}} C \to A$, the quantum isochoric cycle $A \to B \xrightarrow{\text{Green}} C \to A$, and the quantum isoenergetic cycle $A \to B \xrightarrow{\text{Purple}} C \to A$ou2016exotic. The classical triangular, classical isochoric and quantum isochoric cycles operate between two baths at fixed temperatures $T_h$ and $T_c$, while the quantum isoenergetic cycle operates with a single bath at $T_h$, where the effective cold temperature $T_c$ is not fixed but is determined by other parameters.
  • Figure 2: Volume - Temperature diagram of ideal gas during a three-stroke classical isochoric cycle. Stroke $A\xrightarrow{}B$ is the isothermal stroke, $B\xrightarrow{\text{Yellow}}C$ is the isochoric stroke, and $C\xrightarrow{}A$ is the adiabatic stroke.
  • Figure 3: Length - Temperature diagram of the particle in an IPW during a three-stroke quantum isochoric cycle. Stroke $A\xrightarrow{}B$ is the isothermal stroke, $B\xrightarrow{\text{Green}}C$ is the quantum isochoric stroke, and $C\xrightarrow{}A$ is the adiabatic stroke.
  • Figure 4: (a) Efficiency in units of $\eta/\eta_c$ and (b) Work output (in meV) for a particle in an IPW undergoing a three-stroke quantum isochoric cycle working as a heat engine at different hot bath temperatures. In (a), the black dashed line corresponds to $\eta_\text{CT}/\eta_c$ from Eq. \ref{['eq:trianeta']} (classical triangular cycle), while the dotted-dashed line shows $\eta_\text{CI}/\eta_c$ from Eq. \ref{['eq:classical isocho eta']} (classical isochoric cycle). In (b), the dashed and dotted-dashed lines indicate the work outputs $W_\text{CT}$ (Eq. \ref{['eq:workmonoatomic']}) and $W_\text{CI}$ (Eq. \ref{['classical isochor work']}) for a monoatomic ideal gas undergoing the classical triangular and classical isochoric cycles, respectively. $L_B$ is the length of the well during the quantum isochoric process and $T_c=1 \text{K}$.
  • Figure 5: Length - Temperature diagram of the IPW for a three-stroke quantum isoenergetic cycle. Stroke $A\xrightarrow{}B$ is the isothermal stroke, $B\xrightarrow{\text{Purple}}C$ is the isoenergetic stroke, and $C\xrightarrow{}A$ is the adiabatic stroke.
  • ...and 7 more figures