Global observables in statistical mechanics
C. J. F. van de Ven
TL;DR
The paper develops a representation-free $C^*$-algebraic framework to formalize macroscopic observables in statistical mechanics, unifying quantum and classical regimes. It constructs a full C*-product over finite regions, forms a quotient by the vanishing sequences to obtain a global observable algebra, and defines the quasi-local algebra as the thermodynamic limit, then introduces the global observables as the relative commutant, highlighting non-commutativity. It also builds a commutative subalgebra of macroscopic averages via gamma-sequences, and shows that this commutative sector corresponds to tail-measurable quantities in the classical limit. The results connect quantum tail observables to classical tail algebras and lay groundwork for continuous field descriptions across finite and infinite volumes, providing a unified bridge between microscopic and macroscopic thermodynamics.
Abstract
This note presents a canonical construction of global observables -- sometimes referred to in the literature as macroscopic observables or observables at infinity -- in statistical mechanics, providing a unified treatment of both commutative and non-commutative cases. Unlike standard approaches, the framework is formulated directly in the $C^*$-algebraic setting, without relying on any specific representation.
