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Sulphur abundances in star-forming regions from optical emission lines: A new approach based on photoionization models consistent with the direct method

Enrique Pérez-Montero, Borja Pérez-Díaz, José M. Vílchez, Igor A. Zinchenko, Asier Castrillo, Marta Gavilán, Sandra Zamora, Ángeles I. Díaz

TL;DR

This study extends the HII-CHI-mistry framework to optical sulfur, introducing a variable S/O grid so that total sulphur abundance, S/H, can be derived consistently with the direct method even when auroral lines are absent. Using Cloudy v.17 grids and a two-step iterative scheme, the method first constrains N/O and O/H/U, then derives S/H with six S/O variants, enabling direct S/H inference from strong lines without relying on ICFs. Validation against a control sample shows HCm6.0 reproduces direct-method abundances within ≲0.05 dex, while application to the MaNGA survey required correcting for diffuse ionized gas in [S II] to avoid biases in S/O at high metallicity. Across diverse environments, the results imply S/O is near solar over a wide metallicity range (8.0 < 12+log(O/H) < 8.7), with mild enhancements at high metallicity likely linked to oxygen depletion onto dust; the method provides a robust, scalable tool for sulfur abundances in large integral-field surveys.

Abstract

The derivation of sulphur chemical abundances in the gas-phase of star-forming galaxies is explored in this work, using the emission lines produced in these regions in the optical part of the spectrum and by means of photoionization models. We adapted the code HII-CHI-mistry to account for these abundances by implementing additional grids of models that assume a variable sulphur-to-oxygen abundance ratio, beyond the commonly assumed solar value. The addition of these models, and their use in a new iteration of the code allows us to use sulphur lines to precisely estimate the sulphur abundance, even in the absence of auroral lines. This approach aligns with the results from the direct method, and no additional assumptions about the ionization correction factor are needed, as the models directly predict the total sulphur abundance. We applied this new methodology to a large sample of star-forming regions from the MaNGA survey, and we explored the variation of the S/O ratio as a function of metallicity, making corrections for the significant contribution from diffuse ionized gas, which particularly affects the [SII] emission. Our results indicate no significant deviations from the solar S/O value in the range 8.0 < 12+log(O/H) < 8.7, where the bulk of the MaNGA sample stays, but also with possible enhancements of sulphur at the high metallicity regime. This may be linked to the depletion of oxygen in the gas-phase due to its incorporation onto dust grains, as it remains when other metallicity indicators independent of this depletion, as S/H itself, are used instead.

Sulphur abundances in star-forming regions from optical emission lines: A new approach based on photoionization models consistent with the direct method

TL;DR

This study extends the HII-CHI-mistry framework to optical sulfur, introducing a variable S/O grid so that total sulphur abundance, S/H, can be derived consistently with the direct method even when auroral lines are absent. Using Cloudy v.17 grids and a two-step iterative scheme, the method first constrains N/O and O/H/U, then derives S/H with six S/O variants, enabling direct S/H inference from strong lines without relying on ICFs. Validation against a control sample shows HCm6.0 reproduces direct-method abundances within ≲0.05 dex, while application to the MaNGA survey required correcting for diffuse ionized gas in [S II] to avoid biases in S/O at high metallicity. Across diverse environments, the results imply S/O is near solar over a wide metallicity range (8.0 < 12+log(O/H) < 8.7), with mild enhancements at high metallicity likely linked to oxygen depletion onto dust; the method provides a robust, scalable tool for sulfur abundances in large integral-field surveys.

Abstract

The derivation of sulphur chemical abundances in the gas-phase of star-forming galaxies is explored in this work, using the emission lines produced in these regions in the optical part of the spectrum and by means of photoionization models. We adapted the code HII-CHI-mistry to account for these abundances by implementing additional grids of models that assume a variable sulphur-to-oxygen abundance ratio, beyond the commonly assumed solar value. The addition of these models, and their use in a new iteration of the code allows us to use sulphur lines to precisely estimate the sulphur abundance, even in the absence of auroral lines. This approach aligns with the results from the direct method, and no additional assumptions about the ionization correction factor are needed, as the models directly predict the total sulphur abundance. We applied this new methodology to a large sample of star-forming regions from the MaNGA survey, and we explored the variation of the S/O ratio as a function of metallicity, making corrections for the significant contribution from diffuse ionized gas, which particularly affects the [SII] emission. Our results indicate no significant deviations from the solar S/O value in the range 8.0 < 12+log(O/H) < 8.7, where the bulk of the MaNGA sample stays, but also with possible enhancements of sulphur at the high metallicity regime. This may be linked to the depletion of oxygen in the gas-phase due to its incorporation onto dust grains, as it remains when other metallicity indicators independent of this depletion, as S/H itself, are used instead.

Paper Structure

This paper contains 13 sections, 4 equations, 9 figures, 2 tables.

Figures (9)

  • Figure 1: Left: Relation between the emission-line ratio $RS3$ with the total oxygen abundance both for the control sample and for different model sequences calculated at a fixed log $U$ = -2.5 and different values of S/O. Right: Relation between the emission line ratio $S2S3$ and log $U$ both for the control sample, as calculated using HCm, and for different model sequences calculated at a fixed 12+log(O/H) = 8.7 (8.1) with solid (dashed) line and different values for S/O.
  • Figure 2: Relation between the $S23$ parameter and the total sulphur abundance both for the control sample and for different model sequences. Left: Models calculated at a fixed 12+log(O/H) = 8.4 and varying log $U$. Right: Fixed log $U$ = -2.5 and different values for the total oxygen abundance.
  • Figure 3: Comparison between the chemical abundances derived by HCm for the selected control sample when at least one auroral line was measured with enough signal-to-noise ratio, At left,12+log(O/H), and at right 12+log(S/H). In both panels $x$ axis represents the total abundances derived following the direct method and $y$ axis the results from HCm using all available emission lines as input. The red solid line represents the 1:1 relation.
  • Figure 4: Comparison between the chemical abundances derived by HCm for the selected control sample considering auroral lines (x axis) and without them (y axis), At left,12+log(O/H), and at right 12+log(S/H). The red solid line represents the 1:1 relation.
  • Figure 5: Left: Relation between 12+log(O/H) and log $U_*$ ((i.e. the ionization parameter calculated assuming a source of fixed $T_*$, in this case popstar model atmospheres) as derived by HCm for those objects in the control sample for which at least one auroral line has been used. The solid line encompasses the values for the models used when only strong lines are used as input. The points are colored according to the values for $T_*$ found by HCm-Teff. Right: Same relation, but comparing the 12+log(O/H) derived by HCm with the log $U$ values found by HCm-Teff (using sources of different $T_*$ with WM-Basic stellar atmospheres).
  • ...and 4 more figures