Convergence in divergent series related to perturbation methods using continued exponential and Shanks transformations
Venkat Abhignan
TL;DR
This work tackles the challenge of divergent perturbation series in quantum atomic problems by applying a parameter-free continued exponential resummation, drawing parallels to Padé-based convergence. By transforming perturbation expansions for He-like ground-state energies, Hydrogen Stark, and Zeeman effects into continued-exponential forms and extracting coefficients from low-order perturbative data (up to $i=9$ or $i=16$ in some cases), the authors achieve rapid convergence and, in many instances, tight bounds or high-precision eigenvalues. They demonstrate performance improvements via Shanks transformations and validate results against established literature, while highlighting the method’s robustness across different perturbation regimes and its placement within a broader resummation framework. The approach offers a simple, parameter-free alternative to Padé approximants for turning divergent series into accurate analytic approximations with potential applicability to other perturbative contexts.
Abstract
Divergent solutions are ubiquitous with perturbation methods. We use continued function such as continued exponential to converge divergent series in perturbation approaches for energy eigenvalues of Helium, Stark effect and Zeeman effect on Hydrogen. We observe that convergence properties are obtained similar to that of the Padé approximation which is extensively used in literature. Free parameters are not used which influence the convergence and only first few terms in the perturbation series are implemented.
